Soft matter Interfaces, Nanoconfinement and Tribology (SIeN)
Confinement of Soft matter (liquids, colloids, polymers, gels, granular materials, and biological materials) plays an important role in life as it affects the functionality of cell membranes, it is essential for nanomedicine, and it plays a significant role in global climate change through precipitation of CO2-binding carbonates in pores and cracks, geomorphological processes of the Earth’s crust, and earthquakes, and even in mineralization within organisms and in man-made enhanced oil recovery. Furthermore, future resources for the water and energy needs of our society, such as supercapacitors for energy storage and water desalination by nanofiltration membranes, rely significantly on the behavior of liquids in nanopores. Motivated by the global challenges of water, energy and health, Dr. Espinosa-Marzal’s research group aims to determine how the properties of soft matter change at interfaces and under nanoconfinement and to elucidate the physical, chemical and mechanical principles that dictate such modified behavior. Understanding the response of these systems is essential in many areas of research including design of biomaterials, fluid engineering, tribology and lubrication, energy storage, water nanofiltration, environmental chemistry, and other separation techniques, as well as for the optimized design of nanomaterials and in geophysics and geochemistry.
The current main research activities in the group can be summarized as follows:
- Scrutinize surface forces and structural and dynamic properties of nanoconfined fluids (e.g. nano-rheology of lubricants, nano-structure of ionic liquids)
- Electrical double layer in nanopores; electrical double layer of ionic liquids on graphene
- Advance the knowledge of molecular-scale lubrication mechanisms of soft matter, including polymer brushes, surfactants, and hydrogels, with the goal to derive a universal relationship between molecular structure and lubrication performance
- Understand and predict nanoscale friction and adhesion
- Rationalize the mechano-chemical processes that occur at mineral-solution interfaces at the nanoscale, as well as its connection to macroscopic geophysical and geochemical phenomena
- Design new methods for surface functionalization to achieve control over surface properties
- Hydrogel mineralization and crystallization pathways
The ultimate goal is to understand how to exploit intermolecular interactions to tailor macroscopic properties. The current research targets both to answer fundamental and scientifically relevant questions and to solve problems that are relevant to applications.
Open positions for graduate and undergraduate students: Interested in an independent project? Contact me.
- Exciting Special Issue “Surface Forces, Adhesion and Friction“, guest editors: Younjin Min, Rosa M. Espinosa-Marzal, and Seong H. Kim. Submit your paper to Colloids and Interfaces, an open access MDPI Journal. Deadline for manuscript submission: 30 April 2019.
- Our research in Hydrogel Lubrication has been recently featured as Cutting Edge Research in the Journal “Tribology & Lubrication Technology” (TLT). Read about it here. Congrats Tooba for an outstanding publication!
- Gus Greenwood has been awarded Bienvenido M. Esmilla Memorial Writing Award in the Spring 2018 ! Well done, Gus!
- Yijue won the first poster award at the Gordon Research Conference on Tribology and was elected as the chair of the next Gordon Research Seminars (GRS) for young investigators that will take place in 2020! 2xCongratulations to Yijue!
- Josue Lopez was awarded the TechnipFMC Fellowship at UIUC in Spring 2018 to recognize his research on mineralized soft matter! Congratulations Josue!
- Check our newest results about the role of water in fault lubrication!
- Submit your paper to Lubricants, an open access Tribology Journal, in the Special Issue “Ionic Liquids: Friction and Lubrication Mechanisms“. Deadline for manuscript submission: 30 June 2018 (extended!).
- Interesting upcoming symposium in Nanotribology -Molecular Mechanisms in Tribology – in October 2018 in Postdam (Germany). Registration is still open.
- Come to our Symposium on Fundamental Studies of Mechanochemical and Tribochemical Processes at Interfaces (255th ACS National Meeting, in New Orleans). Deadline for the Call for Papers is October 23, 2017 for the COLL Division.
- Ionic Liquids at Interfaces and their Tribological Behaviour. Rosa M. Espinosa-Marzal, Mengwei Han, Andrea Arcifa, Antonela Rossi, Nicholas D. Spencer. Chapter in the Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Elsevier. DOI: 10.1016/B978-0-12-409547-2.13857-0 (2017).